***DELETIA***
Piston planes are for some reason still using it.
***DELETIA***
We're using it (here in the US) because of the FAA aircraft certification standards (which haven't been updated in decades for large swaths of the fleet) for the airframe/engine combinations. It's not as simple as saying "you can use unleaded fuel"; it has implications for the airframe manufacturer as well as the engine manufacturer to get their agreement or reengineereing investment to ensure their liability concerns are addressed.
Unleaded fuels (premium mogas or 'motor gas') are available for use under what's called a "Supplemental Type Certificate", but, as JB points out, the volatiles and other additives are unstable over long-term storage periods, which, obviously can be detrimental to safety of flight. There is a project underway for replacing the 100 octane low lead formulations with a lead-free additive, but since the embedded interests: DoD (which still consumes a measurable amount of the production), refiners, distribution chains, marketing...with us consumers at the bottom of the barrel...and the need to prove that the unleaded replacement meets the ANSI and Mil-Standards for aviation gasoline, it's a complex and time-consuming (it's been going on for a decade) task. Just a taste:
https://www.avweb.com/?s=unleaded+fuelSecond is that avgas is stable and has zero ethanol. Aircraft fuel tanks, piping, fittings, valves, are Aluminum. Ethanol loves to react with Aluminum. Not good for aircraft, not to mention the approved flexible seals and gaskets in the fuel delivery chain are not ethanol resistant; we're getting there, but inertia in cleaning out old stock is a financial question. Again, getting replacement seals, etc. certified and ethanol resistant (and traceable...counterfeit parts are not just discovered for commercial jets...it's a problem for general aviation too....) for use in aircraft is part of that issue.
Third is that there is just one manufacturer of TEL (tetraethyl lead) in the UK. One. TEL is a nasty chemical. Transport is an issue. Remnants in the ground are long-lasting. It's UGLY with a silent F. The sooner it's gone, the better. That being said...it's up to the federal government (in the US), the DoD, and the invested interests to make progress to get rid of it. The amount in 100LL avgas is minimal, but, it's still there.
FWIW, if you are near a general aviation airport...many of them will be happy to sell you 5 gallons in a jerry can that you can use to fill your europa tank and be assured that the gas will be just fine next spring. Been doing that for years...and believe or not...the car runs just fine on avgas.