It's a pressurized system so 100C is not fatal by any means. I've had mine up to 105C in traffic with the AC on (because I had a useless, slim rad fan).
So some questions:
What thermostat are you using?
You can get 71C/160F, 75C/168F, 80C/178F, 85C/180F, 88C/190F
71/160 works fine if you only drive in summer. If you drive in cool weather (below 0C/32F) a better choice is a 75/168 or 80/178.
Are you using antifreeze?
Even in the sunshine belt, "antifreeze" is a good idea as it also raises the coolant's boiling point.
Rad has been cleaned or replaced?
Copper rads cool better at low air speeds. Aluminium rads are much lighter and, surprisingly cheap now. If you bought a new aluminium rad, make sure it isn't too thin and that it has a functioning baffle.
Rad fan?
We have discussed this ad naseum. Whatever I said before, still goes.