Problem solved. I should get Wally of the Week award for not spotting this earlier, but not even a Weber tuning specialist who spent about two hours trying to get the slow running working, spotted this.
He did however diagnose that the butterflies were not closing fully, told me to ease the two screws holding the butterfly, centralise them, then make sure that they do not stick when opening or closing, then screw them tight.
What he did not realise, which I find strange for a Weber specialist, is that the secondary venturis were not fitted to either 40DCOE.
I had the right 4.5 venturis with the screw fit, not the spring fit, amongst my collection of Weber parts, so after fitting them, the car ran perfectly.
Now I have to cure clutch slipping, gear selection very difficult, overheating, oil leak, slow running etc. etc, but at least I have a engine which runs sweetly.