With the stock set-up, castor (and camber) are not adjustable. Camber you can adjust by fitting adjustable upper arms. Castor is more complicated because the trunnion is fixed in one plane by its screw thread. Trying to “shim” it sideways will just adversely load the trunnion causing it to wear (more) quickly. You would have to replace the trunnion with a spherical joint as they did with later Caterhams.
Before going that way, 99.9% of the time, if the castor or camber are off at the front, something is bent. Both the stock upright and stock a-arms are designed to fold first to help protect the chassis. I first made adjustable arms before I realized that my fine-looking uprights were bent. Fit new uprights and stock arms, and everything was back in spec.