I know from being in the industrial heating systems business (kiln building) that measuring temperature accurately can be quite difficult.
Measuring temperature (electrically) accurately............
Surely measuring anything with a mechanical sensor (mercury or the wax probe thingy with the long capillary tube surrounded with coiled wire) is more accurate, but less convenient.
I knew something was amiss as the gauge was recording 130'C but the expansion tank was cold, and the filler cap was not pressurised. At standard pressure, pure water boils at 100'C, if pressurised that can rise to say 120'C, but there was no pressure, it came up to temp far too quickly, and the top rad hose had only started getting hot = the thermostat had only just opened to allow free coolant circulation. I don't know how antifreeze affects the boiling point of water. I know it lowers the freezing point, that is its purpose, but I don't know how it affects the boiling point.
I worked out that the pump sucks water from the radiator, pressurising everything north or upstream of the pump, so I knew it was not at 130'C, it just did not add up.
Anyway, the new sensor seems to be performing as expected.